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These redirect output. The single right arrow redirects from standard output to a new file. The double right arrow appends the standard output to a file. The pipe takes standard output and uses it as the argument to a command.
lightning:~>ls | grep explorer.exe
This would redirect the output from the ls command and use it as the argument to the grep command. It would return any line, in this case file, that contains the string explorer.exe.
lightning:~>ls >> dir_file
Here the output of ls would be put at the end of a file named dir_file
lightning:~>ls > dir_file
This would redirect the output of ls and put it in the new file named dir_file. Note that this will overwrite the file if it already exists.